Macromonomers from AGET Activation of Poly(n-butyl acrylate) Precursors: Radical Transfer Pathways and Midchain Radical Migration
نویسندگان
چکیده
منابع مشابه
On the Thermal Self-Initiation Reaction of n-Butyl Acrylate in Free-Radical Polymerization
This experimental and theoretical study deals with the thermal spontaneous polymerization of n-butyl acrylate (n-BA). The polymerization was carried out in solution (n-heptane as the solvent) at 200 and 220 ◦C without adding any conventional initiators. It was studied with the five different n-BA/n-heptane volume ratios: 50/50, 70/30, 80/20, 90/10, and 100/0. Extensive experimental data present...
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ژورنال
عنوان ژورنال: Macromolecules
سال: 2012
ISSN: 0024-9297,1520-5835
DOI: 10.1021/ma301233v